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Understanding and Quantifying the Impact of Solute-Solvent Van der Waals Interactions on the Selectivity of Asymmetric Catalytic Transformations
The majority of enantioselective organocatalytic reactions occur in apolar or weakly polar organic solvents. Nevertheless,...
Implementing magnetic properties on demand with a dynamic Lanthanoid-Organic Framework
We present the synthesis of a lanthanoid-organic framework (LOF) featuring a dynamic structure that exhibits tunable magne...
Surmounting Instability of Atomically Precise Metal Nanoclusters Towards Boosted Photoredox Organic Transformation
Atomically precise metal nanoclusters (NCs) have recently been unleashed as an emerging sector of metal nanomaterials but ...
Deciphering endogenous SUMO-1 landscape: a novel combinatorial peptide enrichment strategy for global profiling and disease association
Small ubiquitin-like modifier (SUMO) plays a pivotal role in diverse cellular processes and is implicated in diseases such...
Palladium-catalysed asymmetric cascade transformations of 4-alken-2-ynyl carbonates to construct complex frameworks
As a class of readily available and multifunctional building blocks, the chemistry of 4-alken-2-ynyl carbonates remains to...
Oriented Catalysis through Chaos: High-Entropy Spinels in Heterogeneous Reactions
High-entropy spinel compounds (HESs), as a typical class of high-entropy materials (HEMs), represent a novel frontier in t...
Hollow core-shell heterojunction TAPB-COF@ZnIn2S4 as high efficient photocatalysts for carbon dioxide reduction
The conversion of carbon dioxide (CO2) into carbon-neutral fuels using solar energy is crucial for achieving energy sustai...
Reactivity of a heterobinuclear heme-peroxo-Cu complex with para-substituted catechols shows a pKa-dependent change in mechanism
In biological systems, heme-copper oxidase (HCO) enzymes play a crucial role in the oxygen reduction reaction (ORR), where...
Chemodynamic covalent adaptable network-induced robust, self-healing, and degradable fluorescent elastomers for multicolor information encryption
Elastomers are of great significance in developing smart materials for information encryption, and their unique self-heali...
Enhancement of photoinduced reactive oxygen species generation in open-cage fullerenes
Photodynamic therapy is an important tool in modern medicine due to its effectiveness, safety, and the ability to provide ...
Amphiphilic Dynamic Covalent Polymer Vectors of siRNA
Dynamic covalent polymers (DCPs) recently emerged as smart siRNA delivery vectors, which dynamically self-assemble through...
Exploring the Diffusion of DNA Strands into Nanoporous Structure for Establishing a Universal Electrochemical Biosensor
The development of universal electrochemical sensing platforms with high sensitivity and specificity is of great significa...
A Machine Learned Potential for Investigating Single Crystal to Single Crystal Transformations in Complex Organic Molecular Systems
The packing of organic molecular crystals is often dominated by weak non-covalent interactions, making their in-situ rearr...
Data-Driven Parametrization of Molecular Mechanics Force Fields for Expansive Chemical Space Coverage
A force field is a critical component in molecular dynamics simulations for computational drug discovery. It must achieve ...
Plasmon Hybridization Model in Molecules: Molecular Jackhammers
We recently demonstrated molecular plasmons in cyanine dyes for the conversion of photon energy into mechanical energy thr...
More π, please: What drives the formation of unsaturated molecules in the interstellar medium?
We present a computational investigation into the fragmentation pathways of ethanolamine (C2H7NO, EtA), propanol (C3H8O, P...
Chemical proteomic profiling of lysine crotonylation by minimalist bioorthogonal probes in mammalian cells
Protein lysine crotonylation has been found to be closely related to the occurrence and development of various diseases. C...
Mechanistic Insights into the Visible-Light-Driven O–Arylation of Carboxylic Acids Catalyzed by Xanthine-Based Nickel Complexes
We present a photocatalytic protocol for the O-arylation of carboxylic acids using nickel complexes bearing C8-pyridyl xan...
2D hexagonal assembly of a dipolar rotor with a close interval of 0.8 nm using a triptycene-based supramolecular scaffold
Controlling the rotation of carbon-carbon bonds, which is ubiquitous in organic molecules, to create functionality has bee...
Kinetic Control Synthesis of Low-Strain Disordered Micro-Nano High Voltage Spinel Cathodes with Exposed {111} Facets
High-voltage LiNi0.5Mn1.5O4 (LNMO) is one of the most promising cathode candidates for rechargeable lithium-ion batteries ...
Enzymolysis-Induced Energy Transfer Co-Assembled System for Spontaneously Recoverable Supramolecular Dynamic Memory
The continuing growth of digital world requires new ways of constructing memory devices to process and store dynamic data,...
Synthesis of Alcohols: Streamlined C1 to Cn Hydroxyalkylation through Photoredox Catalysis
Naturally occurring and readily available α-hydroxy carboxylic acids (AHAs) are utilized as platforms for visible light-me...
Synthesis of Constrained Bicycloalkanes through Bibase-Promoted Brook rearrangement/Radical-Polar Crossover Cyclization
Highly constrained bicyclic scaffolds are ubiquitous and attracting increasing interest in pharmaceutical and biotechnolog...
Structure-Aware Dual-Target Drug Design through Collaborative Learning of Pharmacophore Combination and Molecular Simulation
Dual-target drug design has gained significant attention in the treatment of complex diseases, such as cancers and autoimm...
Polymer Design for Solid-State Batteries and Wearable Electronics
Solid-state batteries are increasingly centre-stage for delivering more energy-dense, safer batteries to follow current li...
Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: Structure-function relationships
The biomass-derived HMF oxidation reaction (HMFOR) holds great promise for sustainable production of fine chemicals. Howev...
Catalytic Asymmetric Intramolecular Propargylation of Cyclopropanols to Access the Cuparane Core
The catalytic asymmetric propargylation of enol(ate) intermediates are well-established methods for the synthesis of α-pro...
Dicobalt(II) helices kill colon cancer cells via enantiomer-specific mechanisms; DNA damage or microtubule disruption
Highly diastereoselective self-assembly reactions give both enantiomers (Λ and Δ) of anti-parallel triple-stranded bimetal...
Picking the tyrosine-lock: chemical synthesis of the tyrosyl-DNA phosphodiesterase I inhibitor recifin A and analogues
The peptide recifin A is the inaugural member of the structurally intriguing new fold referred to as a tyrosine-lock. Its ...
Repurposing a Supramolecular Iridium Catalyst via Secondary Zn···O=C Weak Interactions between Ligand and Substrate Leads to ortho-selective C(sp2) ̶ H Borylation of Benzamides with Unusual Kinetics
The iridium-catalyzed C ̶ H borylation of benzamides typically leads to meta and para selectivities using state-of-the-art...
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