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Arylation of C=C bonds via non-cross-coupling reactions: historical evolution of the Meerwein arylation mechanisms
Arylation of C=C bonds via non-cross-coupling reactions: historical evolution of the Meerwein arylation mechanisms
The arylation of olefines had a milestone year in 1939 when Hans Meerwein (1879–1965) reported that olefins could re...
The chemistry behind paper restoration: diagnostic techniques and cutting-edge innovation
The chemistry behind paper restoration: diagnostic techniques and cutting-edge innovation
The conservation of ancient paper and manuscripts is a complex and evolving field that combines historical understanding, ...
Painting conditioned by chemistry: the case of Egyptian and ultramarine blue pigments
Painting conditioned by chemistry: the case of Egyptian and ultramarine blue pigments
Painting, from its beginnings over 30,000 years ago, has been conditioned by the availability of pigments, whether mineral...
The origin of the postulates in the Bohr model of the hydrogen atom
The origin of the postulates in the Bohr model of the hydrogen atom
This lecture text introduces the Bohr model of the hydrogen atom in a historical context. Danish physicist Niels Henrik Da...
Design of experiments for cost optimization of a glucose assay using a coupled enzymatic reaction: a practical laboratory course
Design of experiments for cost optimization of a glucose assay using a coupled enzymatic reaction: a practical laboratory course
Statistical design of experiments (DoE) is a key method for the systematic planning, execution, and analysis of experiment...
Catalytic methods of analysis: catalymetry – the inorganic sister of enzymatic analysis
Catalytic methods of analysis: catalymetry – the inorganic sister of enzymatic analysis
Catalytic methods for determination of inorganic ions are frequently labelled as catalymetry. It is the analogue of enzyma...
Correction: A Lewis basic CeO2 cocatalyst expedites two-electron air electroreduction at the theoretical limit
Correction for ‘A Lewis basic CeO2 cocatalyst expedites two-electron air electroreduction at the theoretical limit’ by Lil...
Foldamer Engineering with Squaramide and Phenanthroline Motifs: Synthesis, Characterisation, and Structural Insights
We report a new class of phenanthroline–squaramide foldamers (1–3) that adopt robust, single-helical conformations in both...
Covalent organic framework membranes for CO2 separation: Recent advances and challenges
Global carbon dioxide (CO2) emissions caused by the massive utilization of fossil fuels continue to rise, exacerbating the...
CRISPR Cas Proteins Coronated AuNP Nanostructure for Enhanced Uptake Efficiency into Cells
Nanotechnologies hold significant promise for biosensing and biomedical applications; however, their effectiveness is ofte...
Structure-guided and evolutionary design of a ratiometric fluorescent probe for field-level detection of pyriproxyfen
A polarity-sensitive fluorescent probe offers accurate, specific and ratiometric detection of pyriproxyfen in tea samples.
Di-π-methane rearrangement in 1-phosphabarrelenes: formation and reactivity of an unprecedented 2-phosphasemibullvalene
The photolysis of 1-phosphabarrelenes, generated from 3,5-diarylphosphinines and benzyne in a [4+2] cycloaddition reaction...
Nitro and nitritosilanes: Do they and can they exist?
Nitrosilanes are unknown, much like the nitro analogues of most metalloids. Their nitrite isomers are better known and eve...
Solution polarity modulated electrochromic devices with tunable colored states
Electrochromic devices (ECDs) hold great promise for applications in displays and smart military camouflage. However, achi...
Latent asymmetry of gate opening and closing in a flexible MOF probed by time-resolved in-situ XRD
Time-resolved in-situ X-ray diffraction reveals a latent asymmetry in the gate-type transitions of the flexible metal-orga...
Monitoring Nucleoside Metabolism in Living Cells with a Nucleobase Analogue via Fluorescence Lifetime Imaging
To overcome challenges in fluorescence labelling of RNA inside living cells we have recently introduced a direct approach ...
Molecular machines for transmembrane ion transport
In nature, cellular metabolism in organisms depends on the spatial compartments of ions, small molecules and macromolecule...
Cost-Effective Copper, Cobalt, and Nickel Catalysts for Methane Conversion: from Greenhouse Gas to Green Chemicals
Methane, as a notorious and potent greenhouse gas, has a greenhouse effect potential that is 25-fold higher than carbon di...
CNC-based Circularly Polarized Luminescence Film with High Dissymmetry Factor
Cellulose nanocrystal (CNC) exhibits significant potential as a matrix for generating circularly polarized luminescent (CP...
Harnessing the power of α-diazo compounds: emerging strategies and expanding applications
α-Diazo compounds have long been recognized as versatile reagents in organic synthesis, traditionally employed in metalloc...
Controlled Chain-Walking Ethylene Oligomerization in Gas-Phase for Hyperbranched Ethylene Oligomers
Gas-phase polymerization is typically employed for the synthesis of high-molecular-weight crystalline polyolefin materials...
Microbial Therapeutics for Cancer: Emerging Strategies and Biomedical Applications
Advancements in synthetic biology and nanotechnology have propelled engineered microorganisms to the forefront as an emerg...
Plasmonic Photothermal Nanomaterials for Solar Steam Generation
Solar steam generation, a sustainable and cost-effective water purification technique, has emerged as a promising solution...
Harnessing Non-Equilibrium Hot Electrons in a Quantum-Engineered Ternary Heterostructure for Sub-ppb C9 Biomarker Detection
Photoactivated sensors offer a safe, low-power alternative to thermal sensors, yet their performance against trace concent...
Macrocycles Composed of Biphenylene and Butadiyne Units with Antiaromatic Character
Herein, we report the synthesis and characterization of π-conjugated macrocycles, with diameters over 2.4 nanometers, comp...
Exploring the protein corona-mediated near-wall confined motion of micro-carriers via total internal reflection microscopy
Protein corona can significantly alter the interfacial physico-chemical characteristics and hydrodynamics of microentities...
Ultraviolet photodissociation of methanethiol (CH3SH): Revealing an S(1D) atom elimination channel
We report time-sliced velocity map imaging studies of the methyl (CH3) and electronically excited sulfur (S(1D)) fragments...
Spontaneous amino-yne click polymerization enabled by pyridinium-activated alkynes toward p-π conjugated ionic polymers
The p-π conjugated polymers have garnered considerable interests owing to their distinctive electronic structures, which a...
A New Generation of N-Heterocyclic Carbene (NHC) Gold-Selenolato Complexes as Potent Anticancer Agents: Distinct Synthetic Routes and Evaluation in 2D and 3D Cancer Models
Two distinct synthetic pathways are disclosed that lead to new coinage metal-selenolato complexes, stabilized by N-heteroc...
Kinase signaling cascades: An updated mechanistic landscape
Here we shed physico-chemical light on major kinase signal transduction cascades in cell proliferation in the Ras network,...
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