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Convenient, Direct, Metal-free, Regioselective and De novo Synthesis of 2,4,5-Trisubstituted Pyrimidines using α-Aryl-β,β-Ditosyloxy Ketones
An efficient and environmental benign approach has been developed for the synthesis of 4,5-diphenylpyrimidin-2-amine from ...
A new colorimetric assay based on gold nanoparticles and gold nanocluster assembly for Ag+ and L-cysteine detection
This study reports a novel colorimetric assay for Ag+ and L-cysteine (L-Cys) detection by Ag+-mediated aggregation of gold...
Penicillium brefeldianum B.O. Dodge, 1933: Insights into its Secondary Metabolites, Pharmacological Active Compounds and Biotechnological Potential
Penicillium brefeldianum is a filamentous fungus known for its ability to produce a wide range of bioactive secondary meta...
NiO sensitized porous ZnSnO3 nanocubes for enhanced formaldehyde gas-sensing performance
As a carcinogen, low concentration and high sensitivity detection of formaldehyde is crucial. NiO sensitized porous ZnSnO3...
Phosphoryl-containing derivatives of 8-hydroxyquinoline for the selective detecting of uranyl cations
Designing of selective ligands for the effective and rapid detection of uranyl cation is an actual problem for the nuclear...
Small extracellular vesicles derived from interstitial cells enhances muscle injury repair and regeneration
Critical limb ischemia (CLI), an advanced stage of peripheral arterial disease, is identified by severe ischemia, rest pai...
Specific detection of high-energy phosphate bonds using an enzyme and framework cascade response system in hierarchically mesoporous UiO-66(Zr)-NH2
The development of an expandable sensing platform that responds to high-energy phosphate bonds in phosphorus-containing bi...
Selective and efficient CoZn@MC bimetallic catalyst for the reductive amination of furfural to furfurylamine
The reductive amination of biomass-derived furfural over non-noble metal catalysts represents a promising but challenging ...
Comparative optimization of Alizarin Red S adsorption on Hyper-cross-linked Resin using Response Surface Methodology and Artificial Neural Network Techniques
Given the extensive use of synthetic dyes across various industries as well as their association with the environmental an...
Correction: Preparation of a polyvinyl chloride superhydrophobic coating with high stability and strong corrosion resistance
Correction for ‘Preparation of a polyvinyl chloride superhydrophobic coating with high stability and strong corrosion resi...
Sericin–Polyethylene Glycol Hydrogel as an Innovative Excipient for Progesterone Delivery: Formulation Development, Characterization, Molecular Docking and Toxicity Evaluation
Sericin (SS), a silk-derived protein, possesses numerous advantages such as biocompatibility and non-toxicity, making it a...
Anchoring Pt clusters with different size on KY zeolite: highly efficient catalytic reforming of n-octane
The size of Pt clusters is intimately related to the catalytic activity and product distribution, yet its effect on the n-...
Recent advances in metal complexes for the photodynamic therapy of cancer.
Photodynamic therapy is a non-invasive medical approach that employs a source of light along with photosensitizer for the ...
BODIPY-carbazoles multichromophoric systems for green LED assisted photodynamic therapy of breast cancer. Synthesis, optoelectronic properties, DFT and antitumor studies
A series of five BODIPY dyes substituted with carbazole(s) (Cz) in different positions and one with an iodine atom in Cz w...
Eco-Friendly Medical Textiles: Bamboo Fabric Functionalized with Microencapsulated Essential Oils
This study investigated the antibacterial properties of bamboo fabric embedded with microcapsules containing essential oil...
Immobilization of high efficient adsorbent in biopolymer hydrogel beads with established interconnected network explored for selective dye adsorption
The removal of persistent and toxic dyes from wastewater is a significant environmental challenge. The present study gives...
Nitrogen-inversion-based racemate aggregation and interenantiomer -stacking-caused solid-state fluorescence enhancement
The solid-state fluorescence of fluorophores is usually weakened or quenched by strong π-π interactions. Here, the solid-s...
Photoinduced Co-catalyzed dehydrogenative cyclization of 2-alkenylphenyl carbonyl compounds and mechanistic insights
In this work, we present a UV-induced 6π-cyclization protocol enabling the synthesis of polysubstituted naphthol skeletons...
Dearomative 2,3-Diamination of Indoles Triggered by Rh(III)-Catalyzed Csp2-H Activation
A Rh(III)-catalyzed dearomative 2,3-diamination of indoles with N-alkoxyamides has been developed. The method provides an ...
An Unexpected Lewis Acid-Catalyzed Cascade Reaction of Bicyclo[1.1.0]butanes with Triazinanes to Biscyclobutenyl Amines
An unexpected In(OTf)3-catalyzed cascade reaction of bicyclo[1.1.0]butanes with triazinanes is reported, providing a serie...
Remodelling Molecular Frameworks via Atom-Level Surgery: Recent Advances in Skeletal Editing of (Hetero)Cycles
Skeletal editing is an emerging approach in synthetic chemistry that enables precise atom-level modifications within molec...
Bridged Rings from Phenolic Feedstocks: Regio- and Diastereoselective Substitution-Hemiketalization Cyclization of Bridged Benzoxocin-4-ones with Grignard Reagents
The efficient and controllable generation of bridged polycycles of structural complexity and diversity from readily avaial...
Access to (Bridged) Bicyclic Ureas through Azocarboxamide-Enabled Enantioselective 1,2-Diamination of α-Branched Cyclic Ketones
Chiral bicyclic ureas are important multi-nitrogen-containing polycyclic frameworks and valuable building blocks in organi...
Palladium-Catalyzed Multicomponent [4+2] Cycloaddtion of 1, 4-Enynes with CO and Arylamines to Access Polycyclic γ-Lactams via Dearomative Rearrangement
Herein we report a novel palladium-catalyzed intermolecular dearomative [4+2] cycloaddition of 1, 4-enynes with CO and ary...
Supramolecular Chiroptical Sensing by Achiral AIE-active Thiols
Rapid and sensitive chiroptical sensing is of great significance for practical applications. Here, a novel rapid supramole...
Synthesis of 2-arylchromeno[2,3,4,5-lmna]phenanthridines through a sequential multicomponent assembly, oxygenation and 6πe electrocyclization reactions
A novel metal-free synthetic method is presented for the 2-arylchromeno[2,3,4,5-lmna]phenanthridines from the one-pot reac...
Giese Reaction of Alkyl Bromides using Amine Carboxyboranes
Amine carboxyborane enabled an efficient halogen atom transfer (XAT) with 1o, 2o, and 3o alkyl bromides, resulting in Gies...
Computational Study on Pd-Catalyzed ipso,meta-Dimethylation of ortho-Substituted Iodoarene: Mechanisms and the Role of Base
Density functional theory (DFT) calculations were performed to study Pd-catalyzed ipso,meta-dimethylation reaction of orth...
Progress in Catalytic Enantioselective Construction of Difluoroalkylated Stereogenic Center
Molecules bearing the difluoroalkyl groups were very important in pharmaceuticals, argrochemicals and materials. In recent...
Synthesis of a cross-chain bridging cryptand
We present two methodologies for synthesizing cross–chain bridging cryptand 1 that incorporates tri- and tetra(ethylene gl...
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