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Tetrahydroxydiboron-mediated radical cyclization of unactivated alkenes toward ring-fused quinazolinones
A tetrahydroxydiboron-mediated radical cyclization of unactivated alkenes under photoinduced conditions was developed to s...
Synthesis and Late-stage C-H Functionalization of Papaverines
An efficient synthesis and late-stage C-H functionalization of papaverine under volatile solvent-free conditions are repor...
Facile route to access N-heterocycles using a Choline chloride-Ethylene glycol-based DES in a dual role
A green, metal-free, efficient, and simple methodology has been described for the synthesis of a series of biologically an...
Recent Advances in Iron-Catalyzed 1,2-Difunctionalization of Alkenes
In recent years, the replacement of precious metal catalysts with iron-based systems in alkene functionalization reactions...
DMSO (dimethyl sulfoxide) as a two-methyl source: C-H (trideutero)methylation of (iso)quinolines and their N-oxides
(Trideutero)methylation is an important process in both chemistry and biology. In this context, DMSO(-d6) has largely been...
Catalytic asymmetric kinetic resolution of 2-ethynylaziridines via nucleophilic ring opening with amines
The enantioselective kinetic resolution of racemic 2-ethynylaziridines via ring opening with amines is realized under the ...
Photocatalytic 1,2-Aminoformylation of Olefins with Bifunctional Oxime Esters
Here, we disclose a metal-free photochemical strategy for the single-step synthesis of β-amido acetals through the regiose...
Rongalite-promoted self-dimerization of 3-acylidene-2-oxindoles: a diastereoselective route to synthesis of bispirooxindoles
A facile and efficient one-pot rongalite-mediated self-dimerization of 3-acylidene-2-oxindoles has been developed for the ...
Effect of Ligand on asymmetric hydrogenation of cyclic N-sulfonyl amines catalyzed by nickel
The present study utilizes density functional theory (DFT) to systematically investigate the effect of ligand on mechanism...
Nickel-Catalyzed Reductive Cross-Coupling of Aziridines and Benzyl Chlorides
A nickel-catalyzed reductive cross-coupling of aziridines and benzyl chlorides was realized by using manganese metal as th...
From BN-Dewar Benzene to BN-Benzvalene: A Computational Exploration of Photoisomerization Mechanisms
This study explores the photochemical conversion of BN-Dewar benzene into BN-benzvalene derivatives, offering a strategic ...
RuII-phosphine catalysed direct synthesis of benzimidazoles via acceptorless dehydrogenative coupling of alcohols with aromatic diamines
We report the synthesis and characterization of a RuII complexes containing amide-based phosphine ligands [o-Ph2P(C6H4)C(O...
Mukaiyama-Michael Reaction: Enantioselective Strategies and Applications in Total Synthesis
The Mukaiyama-Michael (M-M) reaction is a powerful approach for carbon-carbon bond formation and can provide access to all...
Halonium and Chalconium Salt-Catalyzed Schiff Condensation: Kinetics and DFT Insights into Organocatalyst Activity Parameters
Schiff condensation between 4-methylbenzaldehyde and 2-aminopyridine, catalyzed by chloronium, bromonium, iodonium triflat...
Recent Progress in C–S Bond Formation via Electron Donor-Acceptor Photoactivation
Recent advancements in C–S bond formation via electron donor-acceptor (EDA) photoactivation have been highlighted. EDA com...
Copper (I) Catalyzed Coupling of Alkynyl Glycosides: Synthesis of Buta 1,3-Diyne Linked Disaccharides and Dinucleosides
Herein we report copper-catalyzed coupling of alkynyl glycosides facilitating the synthesis of buta 1,3 diyne linked disac...
Correction: A novel platinum(II) complex with a berberine derivative as a potential antitumor agent targeting G-quadruplex DNA
Correction for ‘A novel platinum(ii) complex with a berberine derivative as a potential antitumor agent targeting G-quadru...
Direct Organocatalytic Chemoselective Synthesis of Pharmaceutically Active Benzothiazole/Benzoxazole-Triazoles
Benzothiazole and benzoxazole heterocyclic rings containing 1,4,5-trisubstituted-1,2,3-triazoles are well-known for their ...
Facile synthesis of the unknown 6,7-dihydrofuro[3,4-c]pyridines and 3,4-diaryloylpyridines from N-propargyl β-enaminones
In this paper, we have uncovered a new reaction of N-homopropargylic β-enaminones, i.e. N-(4-phenyl-3-butynyl)-β-enaminone...
A silicon rhodamine 1,2-dioxetane chemiluminophore for in vivo near-infrared imaging
Near-infrared (NIR) chemiluminescent probes have attracted increasing attention in recent years due to their attractive pr...
I2-Catalyzed Benzylation of NH-Sulfoximines with Diarylme-thanes and Al-kylarenes
A practical transition metal-free approach for the selective benzylation of NH-sulfoximines has been disclosed by using si...
High-yielding Total Synthesis of Embelin, Rapanone, and Irisoquin A, D, F
A simple and sustainable three- and four-step sequences of di-OH-protection/mono-OMe-deprotection/OrgRC and di-OH-protecti...
Regioselective synthesis of 5-azaindazoles based on the intramolecular amination reaction of 5-acyl-4-pyridones with hydrazines
The labile tautomerism of N-unsubstituted 5-acyl-4-pyridones, which exist in the form of 4-pyridone or 4-hydroxypyridine d...
Retraction: Thiourea dioxide promoted efficient organocatalytic one-pot synthesis of a library of novel heterocyclic compounds
Retraction of ‘Thiourea dioxide promoted efficient organocatalytic one-pot synthesis of a library of novel heterocyclic co...
Monoterpenoid Selenophenes Derived from (-)-Carvone with GPx-like activity
Organoselenium compounds have been recognized as potential therapeutic agents against several diseases. Specifically, the ...
Cp*Co(III)-catalyzed ortho-alkylation/alkenylation of anilides
A highly practical and efficient Cp*Co(III)-catalyzed C–H alkylation/alkenylation reaction of anilides with maleimides and...
Palladium-catalyzed cross-coupling of arylcarboxylic acid 2-pyridyl esters with terminal alkynes
In the presence of Na2CO3 the combination of PdCl2(dppf), dppp and CuI catalyzes the decarbonylative coupling of arylcarbo...
Synthesis and biological evaluation of lipid A derived from commensal Bacteroides
The inflammation-inducing properties of lipopolysaccharides (LPS) of gram-negative bacteria reside in its lipid A moiety. ...
Lighting up Mycobacteria with fluorescent membrane targeting peptides
We report a series of fluorescent probes based on mycobacteria membrane peptides, containing either L- or D-amino acids wh...
Electrochemical Ruthenium-Catalyzed Annulation of Benzamidines Hydrochloride and Internal Alkynes: A Sustainable Route to 1-Aminoisoquinolines
A novel electrochemical process for the synthesis of 1-aminoisoquinoline derivatives through the Ru(III)-catalyzed annulat...
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